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This step might involve acid-base catalysis by the active-site cysteinyl thiolate (which could explain an effect of the second cysteinyl residue), and/or the conserved lysine residue, yielding GS in analogy to glutathione transferases (Fig
10.1016/j.tifs.2019.11.020 Trends Food Sci
The main endogenous antioxidant defense is provided by glutathione (GSH)
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